Dianion aggregates derived from lithiation of N-silyl allylamine |
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Authors: | Williard P G Jacobson M A |
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Institution: | Department of Chemistry, Brown University, Providence, Rhode Island 02912, USA. paul_williard@brown.edu |
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Abstract: | reaction: see text] Three different N-silyl-protected allylamines, i.e., N-TMS, N-TBDMS, and N-TIPS allylamine, were lihtiated by reaction with excess n-butyllithium. Crystallization of the resulting dianions and X-ray structure determination yields three uniquely different aggregates. |
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