Assembly of hydrogen bonded diamondoid networks based on synthetic metal-organic tetrahedral nodes |
| |
| Authors: | Ma Bao-Qing Sun Hao-Ling Gao Song |
| |
| Affiliation: | State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China. |
| |
| Abstract: | Reaction of Mn(ClO4)2 or Co(PF6)2 with 4,4'-dipyridine-dioxide (dpdo) produced novel molecular species [M(dpdo)4(H2O)2]2+, which hold a tetrahedral configuration notwithstanding their octahedral environment around the metal centers. The tetrahedral moieties are further assembled through hydrogen bonds between peripheral NO ends of dpdo ligands and coordinated water molecules, giving rise to 3D diamondoid networks. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
