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| GC-MS测定仲丁醇、富马酸二甲酯、咪唑和芝麻酚 | |
| 引用本文： | 李晶,耿永勤,魏玉玲,陈建华,邓立花,徐济仓. GC-MS测定仲丁醇、富马酸二甲酯、咪唑和芝麻酚[J]. 光谱实验室, 2013, 30(5): 2487-2491 |
| 作者姓名： | 李晶 耿永勤 魏玉玲 陈建华 邓立花 徐济仓 |
| 作者单位： | 1. 云南烟草科学研究院 昆明市高新技术开发区科医路41号 650106;工业控制技术国家重点实验室 浙江大学智能系统与控制研究所 杭州市浙大路38号 310058 2. 云南烟草科学研究院 昆明市高新技术开发区科医路41号 650106 3. 云南农业职业技术学院 昆明市茭菱路128号 650031 |
| 基金项目： | 云南中烟公司科研资助项目 |
| 摘 要： | 建立了气相色谱串联质谱（GC-MS）准确、快速测定香精香料中仲丁醇、富马酸二甲酯、咪唑和芝麻酚的分析方法.样品经甲醇超声提取15min后,通过Agilent DB-WAX（0.25mm×30m×0.25μm）色谱柱分离,质谱进行定性,外标法对于4种目标物质进行定量分析.实验结果表明,在0.5-20mg/L的范围内,4种物质具有较好的线性,各待测物质的线性相关系数均大于0.9990,检出限为0.02-0.12mg/L,在1,5mg/L和10mg/L 3个加标水平条件下,4种禁限用物质的平均回收率为88.0％-113.1％,相对标准偏差为0.32％-6.53％.该方法前处理简单,灵敏度高,线性相关性好,重复性佳,可以满足香精香料中4种物质的同时检测. |
| 关 键 词： | 气相色谱串联质谱 仲丁醇 富马酸二甲酯 咪唑 芝麻酚 分离 |
Determination of s-Butanol, Dimethyl Fumarate,Imidazole, Sesamol by Gas Chromatography-Mass Spectrometry |
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| LI Jing , GEN Yong-Qin , WEI Yu-Ling , CHEN Jian-Hua , DENG Li-Hua , XU Ji-Cang. Determination of s-Butanol, Dimethyl Fumarate,Imidazole, Sesamol by Gas Chromatography-Mass Spectrometry[J]. Chinese Journal of Spectroscopy Laboratory, 2013, 30(5): 2487-2491 | |
| Authors: | LI Jing GEN Yong-Qin WEI Yu-Ling CHEN Jian-Hua DENG Li-Hua XU Ji-Cang |
| Affiliation: | a(Yunnan Academy o,f Tobacco Science,Kunming 650106 ,P. R. China) b (State Key Laboratory of Industrial Control Technology,Institute of Cyber-Systems and Control, Z he jiang University, Hang zhou 310058, P. R. China ) c(Yunnan Vocational and Technical College of Agriculture,Kunming 650031 ,P. R. China) |
| Abstract: | A gas chromatography coupled with mass spectrometry as detector （GC-MS） was established for the separation and determination of 4 substances （s-butanol, dimethyl fumarate, imidazole,sesamol） in flavor and fragrant samples. After extracted by HPLC methanol, the target compounds were separated on an Agilent DB-WAX capillary column （0.25mm×30m×0.25μm）. Selected ion monitoring （SIM） mode of GC-MS was used in quantitation. It＇s exhibited that there was a good linear relationship （〉0. 9990） ranged from 0. 5 to 25mg/L and the limits of detection was in range of 0. 02--0.12mg/L. The average recoveries at three levels were in the range of 88.0%-- 113.1% with the relative standard deviations （RSD）ranged from 0. 32% to 6. 53%. This simple method can be used to determine 4 substances in flavor and fragrant samples simultaneously. |
| Keywords: | Gas Chromatography-Mass Spectrometry（GC-MS） s-Butanol~Dimethyl Fumarate Imidazole Sesamol Separation |
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