Preconcentration of noble metals with the POLYORGS 4 complexing sorbent under the action of microwave irradiation |
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Authors: | O B Mokhodoeva G V Myasoedova I V Kubrakova |
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Institution: | (1) Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow, 119991, Russia |
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Abstract: | The sorption of Au(III), Pd(II), Pt(IV), Rh(III), and Ir(IV) with the POLYORGS 4 complexing sorbent in the static mode was studied at room temperature and on thermal and microwave heating. It was demonstrated that the sorption of noble metals from 1 M HCl and 1 M HNO3 solutions can be substantially accelerated under the action of microwave irradiation. Based on the obtained data, the conditions of the group preconcentration of noble metals for their subsequent determination by the ETAAS and ICP AES methods were selected. The preconcentration procedure was used for the analysis of certified reference material SARM-7B (platinum-containing ore), VT-1 (copper-nickel sulfide ore), and the alloy of copper with noble metals. |
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