Supercritical phase equilibria involving solids |
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Authors: | R Koningsveld GAM Diepen |
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Institution: | DSM, Research & Patents, Geleen, The Netherlands |
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Abstract: | The solubility of solids in supercritical solvents is reviewed in a phenomenological discussion of binary and ternary systems containing one highly volatile component. Solubility and selectivity are greatly determined by the course of the binary critical curves, the ternary critical end-point curves, and the locations of the triple points of the solids. The mean-field lattice-gas model is used to review some important molecular parameters. |
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