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A kinetic approach to homogeneous Ziegler type polymerization. Steady state |
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| Authors: | Maria Merces Marques C. Costa F. Lemos F. Ram?a Ribeiro A. R. Dias |
| Affiliation: | (1) Centro de Química Estrutural, Instituto Superior Técnico, Av. Rovisco Pais 1, 1096 Lisboa Codex, Portugal;(2) Centro de Engenharia Biológica e Química, Dept. Eng. Química, Instituto Superior Técnico, Av. Rovisco Pais 1, 1096 Lisboa Codex, Portugal |
| Abstract: | In this paper we present a kinetic approach to the analysis of steady-state homogeneous Ziegler-Natta polymerization activity data. The influence of the number of monomeric species that are coordinated to the active site on the apparent rate law is discussed and the equations are fitted to the experimental results. |
| Keywords: | Olefin polymerization Ziegler-Natta catalysis |
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