Interfacial Polycondensation in Aqueous and Non-Aqueous Systems |
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Authors: | Naoya Ogata Kohei Sanui Takao Onozaki Shoehei Imanishi |
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Institution: | Department of Chemistry , Sophia University , 7 Kio-Cho, Chiyoda-Ku Tokyo, Japan , 102 |
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Abstract: | Abstract Interfacial polycondensation in aqueous and non-aqueous systems has been investigated in order to synthesize various polyamides having functional groups. Rigid aromatic polyamides having pyridine moieties (PPy) were synthesized by interfacial polycondensation using an aqueous system and the solution properties of PPy in concentrated sulfuric acid were investigated in terms of solution viscosity and lyotropic behavior. Interfacial polycondensation in a non-aqueous system using two immiscible solvents was found to be useful for the synthesis of aromatic polyesters and copolyesters. |
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