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Some Tetrahedral Coordination Polymers of Zinc(II), Cadmium(II), and Mercury(II) Involving 4-Aminomethylpyridine
Authors:Ishar Singh Ahuja  Rangarajulu Sriram  Chhote Lal Yadava
Institution:Chemistry Department , Banaras Hindu University , Varanasi, 221005, India
Abstract:Abstract

Analytical data and infrared spectral measurements down to 200 cm?1 on the 1:1 compounds formed by the interaction of zinc(II) and cadmium(II) thiocyanates and mercury(II) chloride and bromide with 4-aminomethylpyridine indicate that the compounds are coordination polymers having tetrahedral stereochemistry with bidentate bridging 4-aminomethylpyridine molecules and terminally bonded halogen/pseudohalogen groups in the solid state.
Keywords:trisubstituted ethylenes  radical copolymerization  alternating copolymers  vinyl acetate copolymers
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