Effect of Temperature on Cononsolvency of Polyvinylpyrrolidone in Water/Methanol Mixture |
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Authors: | Moez Guettari Riadh Gomati Abdelhafidh Gharbi |
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Institution: | 1. Laboratoire de Physique de la Matière Molle, Faculté des Sciences de Tunis , Campus Universitaire , Tunisia;2. Laboratoire de Physique de la Matière Molle, Faculté des Sciences de Tunis , Campus Universitaire , Tunisia;3. College of Sciences , Al-Jouf University , Sakaka, Al-Jouf, Kingdom of Saudi Arabia |
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Abstract: | The behavior of polyvinylpyrrolidone in mixed water/methanol solvents was studied by rheoviscosimetry over a temperature range of 20°C–40°C. For the lower temperatures of this range, the intrinsic viscosity variation of the polymer vs. methanol molar fraction shows structural transitions (coil–globule–coil). This transition, which is usually attributed to the cononsolvency phenomenon, agrees with our previously published results obtained by dynamic light scattering. For higher temperatures, near 40°C, the intrinsic viscosity increase shows an expansion of the polymer over the alcohol molar fraction range 0.2 < X A < 0.5. This last result can be attributed to the water/alcohol complex destruction under temperature increase. The “excess viscosity” of the polymer-mixed solvents vanishes with increasing temperature and becomes positive at 40°C. So, the polymer chain tends to transit from a globular to an ideal chain in the middle composition range of the mixed solvents. |
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Keywords: | complex cononsolvency mixed solvents polyvinylpyrrolidone rheology temperature |
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