Synthesis, X-ray diffraction study, and ionic conductivity of new AB2O6 pyrochlores |
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Authors: | A. Castro I. Rasines X. M. Turrillas |
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Abstract: | The oxides A(Ti0.5Te1.5)O6 (A = K, Rb, Cs, Tl), A(Ti0.5W1.5)O6 (A = Rb, Cs, Tl), and Cs(B0.5W1.5)O6 (B = Zr, Hf) have been obtained as polycrystalline powders giving X-ray diffraction patterns characteristic of defect cubic pyrochlores, space group (No. 227), Z = 8. The best discrepancy R factors, from 0.0265 for Rb(Ti0.5Te1.5)O6 to 0.0554 for Cs(Zr0.5W1.5)O6, were obtained for the B cations randomly distributed at 16(d), A ions at one quarter of 32(e), and oxygen atoms at 48(f) positions. A linear relationship is observed between the a unit cell parameters and the ionic radii of the A cations, as well as the average ionic radii of the B atoms. The results of electrical resistivity measurements for A(Ti0.5Te1.5)O6 (A = K, Rb, Cs, Tl) are given. |
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