Dipolar magnetic field effects in NMR spectra of liquids |
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| Authors: | C Gayathri AA Bothner-By PCM Van Zijl C Maclean |
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| Institution: | Department of Chemistry, Carnegie-Mellon University, Pittsburgh, Pennsylvania 15213, USA;Department of Physical Chemistry, Free University of Amsterdam, 1081 HV Amsterdam, The Netherlands |
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| Abstract: | Dipolar magnetic field effects have been detected in the NMR spectra of coronene and methylpyropheophorbide in liquid solution. These effects arise from the partial molecular alignment induced by the magnetic field. Both 1H-1H and 13C-1H couplings have been detected. For both compounds the anisotropy in the diamagnetic susceptibility is calculated. |
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