A kinetic study of the infrared multiphoton dissociation of s-trioxane |
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| Authors: | X Zheng Z Xu F Kong |
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| Institution: | Department of Chemistry, Chinese University of Science and Technology, Hefei, Anhui, People''s Republic of China |
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| Abstract: | The IR multiple photon dissociation of s-trioxane is reported. The molecule is dissociated with high efficiency at low fluences (i.e. 6 J cm?2) At high s-trioxane pressures, the dissociation is enhanced via V-V processes. Addition of He results in V-T deactivation of the energized molecule. The dissociation is well described by RRKM theory. |
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