Collinear quantum mechanical probabilities and rate constants for the Br + HCl(ν = 2, 3, 4) reaction using hyperspherical coordinates |
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| Authors: | Jack A Kaye Aron Kuppermann |
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| Institution: | Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, California 91125, USA |
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| Abstract: | Calculations of quantum mechanical probabilities and rate constants for the collinear reaction Br + HCl(ν = 2,3,4) → BrH + Cl, Br + HCl(ν < ν) were performed using hyperspherical coordinates. Removal of vibrationally excited HCl proceeds mainly by reaction to a nearly degenerate HBr state. Processes for which a large change in the internal enery occurs have low probabilities. |
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