The electron—ion recombination coefficient in CO2 and NH3. Deviations from a linear density dependence at elevated pressures |
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| Authors: | David A Armstrong EricS Sennhauser John M Warman Ulrich Sowada |
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| Institution: | Department of Chemistry, University of Calgary, Calgary Alberta, Canada T2N 1N4;Interuniversity Reactor Institute, 2629 JB Delft, The Netherlands |
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| Abstract: | The rate coefficient for electron—ion recombination at 292 K rises to a value of 7 x 10?5 cm3 s?1 in CO2 at 13 x 1019 molecule cm?3, but is non-linear with density above 8 x 1019 molecule cm?3. In ammonia it passes through a definite maximum of 7 x 10?5 cm3 s?1 at 2.4 x 1019 molecule cm?3 |
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