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Rotationally inelastic scattering from surfaces CO(g) + LiF(OO1) |
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| Authors: | JW Hepburn FJ Northrup GL Ogram JC Polanyi JM Willamson |
| Institution: | Department of Chemistry, University of Toronto, Toronto, Canada M5S IAI |
| Abstract: | The rotationally inelastic scattering of a supersonic, rotanonally cold (TrotI = 4–30 k) CO molecular beam from a clean LiF(001) surface has been investigated by VUV laser-induced fluorescence. Rotational accommodation was incomplete for surface temperatures 350 <Ts < 900 K. The degree of accommodation decreased with Ts and was independent of collision energy. |
| Keywords: | Present address: Lawrence Berkeley Laboratories University of California Berkeley California 94720 USA |
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