Transformation of spin-orbit excited states of halogen atoms in the chemical reactions F + Br2 → BrF + Br,I*+ Br2 → IBr + Br,and Br + IBr → Br2 + I |
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| Authors: | E.B. Gordon A.I. Nadkhin S.A. Sotnichenko I.A. Boriev |
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| Affiliation: | Quantum Systems Laboratory, Institute of Chemical Physics, Academy of Sciences, 142432 Chernogolovka, Moscow Region, USSR |
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| Abstract: | The small laser pulse gain method, based on photochemical Br and I lasers, is used to probe 2P3/2 and 2P1/2 states of iodine and bromine atoms in the reactions F + Br2 → BrF + Br (I), I(2P1/2) + Br2 → IBr + Br (II), and Br + IBr → Br2 + I (III). The results obtained are capable of formulating a conservation rule for the spin-orbit excited state. |
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