Photophysical properties of mixed-ligand ruthenium(II) complexes [Ru(1,10-phenanthroline)n {2-(2-pyridyl)quinoline}3-n] 2+ (n = 0, 1, 2, or 3) |
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| Authors: | Alan T. Cocks Raymond D. Wright Kenneth R. Seddon |
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| Affiliation: | Chemistry Division, Central Electricity) Research Laboratories, Leatherhead, Surrey KT22 7SE, UK;Oxford-Imperial Energy Group, Inorganic Chemistry Laboratory University of 0xford, Oxford OX1 3QR, UK |
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| Abstract: | Electronic absorption, emission, and excitation spectra together with lumincscence lifetimes, have been measured for the mixed-ligand 1,10-phenanthroline/2-(2-pyridyl)quinoline complexes of ruthenum(II). Charge-transfer absorption and emitting states appear to be located on the individual ligands and there is evidence that energy transfer from the phenanthroline absorption state to the pyridylquinoline emitting state occurs. |
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