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Non-exponential decay of the fluorescence from the 1Δg state in liquid oxygen at high excitation intensities
Authors:H. Klingshirn  B. Faltermeier  W. Hengl  Max Maier
Affiliation:Naturwissenschaftliche Fakultāt II - Physik, Universitāt Regensburg, Germany
Abstract:The 1Δg state of liquid oxygen (natural O2 and 18O2) was excited by intense Nd: YAG laser pulses. The observed fluorescence decay is non-exponential and depends on pump laser intensity. Various decay channels of the 1Δg state are discussed. The energy pooling reaction 1Δg + 1Δg1Σ+g + 3Σ?g is verified experimentally. Values f constant of liquid natural O2 and 18O2 are given.
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