IR laser-induced decomposition of dialkoxyalkanes |
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Authors: | James E Kuder Douglas R Holcomb |
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Institution: | Celanese Research Company, Summit, New Jersey 07901, USA |
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Abstract: | Infrared multiphoton excitation of dimethoxymethane and related compounds results in initially very high conversions with subsequent failure of the reaction to go to completion. This behavior is attributed to a free radical chain decomposition with inhibition of further reaction by collisional deactivation or trapping of intermediates by reaction products. |
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