Level-to-level vibrational energy transfer studies: energy dependence and observation of product species for azulenes(S0, Evib) + CO2 |
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Authors: | John R. Barker Michel J. Rossi Jack R. Pladziewicz |
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Affiliation: | Department of Chemical Kinetics, SRI International, Menlo Park, California 94025 USA |
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Abstract: | V—V energy transfer from a large molecule excited to vibrational energies of chemical interest has been demonstrated by detection of ≈ 1.5% yield of CO2(001) due to energy transfer from azulene (Evib ≈ 30600 cm?1. Also, the average enery lost per collision by azulene was measured as a function of Evib, and the rate constant for CO2(001) deactivation by azulene was determined. |
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