EPR study of the NO2+3 radical in irradiated K(UO2)(NO3)3 and K2(UO2)(NO3)4 single crystals |
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| Authors: | TK Gundu Rao KV Lingam BN Bhattacharya |
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| Institution: | R.S.I.C., Indian Institute of Technology, Bombay 400 076, India;Physics Department, Indian Institute of Technology, Bombay 400 076, India |
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| Abstract: | A new radical observed at low temperature in γ-irradiated K2(UO2)(NO3)4 single crystals has been tentatively assigned to a hitherto unknown oxyanion radical, NO2+3. The assignment and the lack of 14N hyperfine structure, together with the g factors which are lower than the free-spin value, are discussed in terms of an orbital level scheme. |
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