The electronic structure of CrO43− as studied by EPR in K2SO4 single crystals |
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| Authors: | Y Ravi Sekhar H Bill |
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| Institution: | Groupe Physico-Chimie du Solide, Sciences II, Université de Genève, 30, Quai E. Ansermet, 1211 Geneva 4, Switzerland |
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| Abstract: | EPR and ENDOR investigations are carried out on irradiated K2SO4 crystals doped with CrO42? ions. They indicate the formation of CrO43? centers interacting with a nearby proton. The identification of the CrO43? centers is based on their g values, the orientation of the g tensor and the symmetry requirements. The results are compared with related studies on MnO42? in K2SO4 and K2CrO4 hosts. |
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