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Ionization of fluoromethanes: CHF3 and CF4. A Greens̀ function study and an (e, 2e) spectroscopic investigation
Authors:R. Cambi  G. Ciullo  A. Sgamellotti  F. Tarantelli  R. Fantoni  A. Giardini-Guidoni  M. Rosi  R. Tiribelli
Affiliation:Dipartimento di Chimica, Università di Perugia, 06100 Perugia, Italy;E.N.E.A. ex CNEN, Centro Nazionale di Frascati, 00044 Frascati, Rome, Italy
Abstract:A Green's function study has been performed on CHF3 and CF4. Theoretical results are compared with (e 2e) spectral data. Previous assignment of valence-shell orbitals is confirmed and a splitting of the innermost ionizations over many shake-up terms in experimental and theoretical results on both molecules.
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