Ionization of fluoromethanes: CHF3 and CF4. A Greens̀ function study and an (e, 2e) spectroscopic investigation |
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| Authors: | R Cambi G Ciullo A Sgamellotti F Tarantelli R Fantoni A Giardini-Guidoni M Rosi R Tiribelli |
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| Institution: | Dipartimento di Chimica, Università di Perugia, 06100 Perugia, Italy;E.N.E.A. ex CNEN, Centro Nazionale di Frascati, 00044 Frascati, Rome, Italy |
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| Abstract: | A Green's function study has been performed on CHF3 and CF4. Theoretical results are compared with (e 2e) spectral data. Previous assignment of valence-shell orbitals is confirmed and a splitting of the innermost ionizations over many shake-up terms in experimental and theoretical results on both molecules. |
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