Electrostatic effects on the migration rates of ions between charged micelles. Consequences for fluorescence quenching |
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| Authors: | Mats Almgren Gudmundur Gunnarsson Per Linse |
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| Institution: | Departments of Physical Chemistry 1 and 3, Chemical Center, University of Lund S-220 07 Lund, Sweden |
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| Abstract: | The rate of exchange of countenons between micelles has been calculated from numerical solutions of the Poisson-Boltzmann equation for micelles in cells of spherical symmetry, and solutions of a steady-state diffusion problem for the ion in the resulting potential. The results indicate a rapid increase of the exchange rate with total amphiphilc concentration, as has been observed. |
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