| 对—乙酰苯基二茂铁的晶体结构 |
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| 引用本文： | 王曼芳 步修仁. 对—乙酰苯基二茂铁的晶体结构[J]. 应用化学, 1990, 7(4): 82-85 |
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| 作者姓名： | 王曼芳 步修仁 |
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| 作者单位： | 厦门大学化学系，南京大学配位化学研究所，南京大学配位化学研究所，南京大学配位化学研究所 厦门 361005 |
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| 摘 要： | 单取代二茂铁化合物,尤其是单取代芳基二茂铁化合物,当芳基为带有各种不同取代基苯时,中心铁原子的氧化还原电势会产生相应的变化,茂环上屹化学位移也明显地与Hammett常数相关。在对-乙酰苯基二茂铁的电化学研究中已经证明,它的氧化势
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| 关 键 词： | 对-乙酰苯基二茂铁 晶体结构 |
| 收稿时间： | 1989-01-06 |
THE CRYSTAL STRUCTURE OF p-FERROCENYLACTEOPHENONE |
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| Wang Manfang,Bu Xiuren,Meng Qingjin,You Xiaozeng. THE CRYSTAL STRUCTURE OF p-FERROCENYLACTEOPHENONE[J]. Chinese Journal of Applied Chemistry, 1990, 7(4): 82-85 |
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| Authors: | Wang Manfang Bu Xiuren Meng Qingjin You Xiaozeng |
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| Affiliation: | Wang Manfang,Bu Xiuren,Meng Qingjin,You Xiaozeng Department of Chemistry,Xiamen University,Xiamen 361005 Coordination Chemistry Institute,Nanjing University,Nanjing210008 |
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| Abstract: | The crystal and melecular structure of p-ferrocenylacetophenone has been determined bythe single crystal X-ray diffractometry. The crystal is orthorhombic and space group P_(bca)with the cell constants a = 7.7342, b = 10.5485, c = 34.0332 A and Z = 8. The analytic resultsshow that both the CP rings are almost parallel. The plane of each ring is tilt 18 from thatof Phenyl ring.The carbon atom of the acetyl group is normal sp~2 hybridization, the anglesaround this carbon is close to 120. One significant result obtained in this structure is that thecarbon to carbon bond length in the CP ring linkedto the phenyl group is longer than C-Clength in the other CP ring. |
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| Keywords: | p-ferrocenylacetophenone crystal structure |
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