| 溴代及胺交联聚苯醚（PPO）膜的气体透过行为 |
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| 引用本文： | 郝建强,贾连达.溴代及胺交联聚苯醚（PPO）膜的气体透过行为[J].应用化学,1990,7(4):57-61. |
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| 作者姓名： | 郝建强 贾连达 |
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| 作者单位： | 中国科学院长春应用化学研究所，中国科学院长春应用化学研究所，中国科学院长春应用化学研究所 长春 130022，长春 130022，长春 130022 |
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| 摘 要： | 对聚苯醚(PPO)进行了苯环溴代、甲基溴代以及胺交联,发现苯环溴代可提高O_2、N_2透过率(P),而选择性(α)基本不变。甲基溴代则相反,P降低、α有明显提高。调节两者比例可得到P、α兼优的O_2、N_2分离膜。甲基溴代后进一步胺交联可得到α更高、耐溶剂的膜材料。
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| 关 键 词： | 聚苯醚 溴代 交联 透过率 气体分离膜 |
| 收稿时间： | 1989-07-22 |
GAS PERMEATION OF AMINE-CROSSLINKED POLY(2,6-DIMETHYLPHENYLENE OXIDE)MEMSRANE |
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| Hao Jianqiang,Jia Lianda,Xu Jiping Changchun Institute of Applied Chemistry,Academia Sinica,Changchun.GAS PERMEATION OF AMINE-CROSSLINKED POLY(2,6-DIMETHYLPHENYLENE OXIDE)MEMSRANE[J].Chinese Journal of Applied Chemistry,1990,7(4):57-61. |
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| Authors: | Hao Jianqiang Jia Lianda Xu Jiping Changchun Institute of Applied Chemistry Academia Sinica Changchun |
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| Institution: | Hao Jianqiang,Jia Lianda,Xu Jiping Changchun Institute of Applied Chemistry,Academia Sinica,Changchun 130022 |
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| Abstract: | Poly(2,6-dimethylphenylene oxide) (PFO) has been brominated and crosslinked withammonia, ethylenediamine, m-phenylenediamine and hexamethylenetetramine. It was foundthat the oxygen permeability of the polymer membrane increased with the aryl-bromine con-tent in BrPPO and decreased with the benzyl-bromine content in BrPPO. NH_3-crosslinkingof BrPPO increased the oxygen permeability. Ethylenediamine-crosslinking of BrPPO increasedthe selectivity of oxygen over nitrogen significantly. Through crosslinking of benzyl-bromi-nated PPO a solvent resistant membrane with high selectivity of oxygen over nitrogen wasobtained. |
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| Keywords: | PPO bromination crosslinking permeability gas separation membrane |
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