Abstract: | A variety of eleclrophilic substitution reactions have been carried out on 4-methoxybenzo[b]-thiophene (IIIa) and 4-benzoyloxybenzo[b ] thiophene (IVa). Substitution occurs in the 7-position of IIIa and, with the exception of bromination, in the 7-position of IVa. Bromination of IVa occurs in the 3-position. Bromination of 4-hydroxybenzo[b] thiophene (IIa) occurs in the 5-position. The nmr spectra of eleven disubstituted benzo[b] thiophenes have been tabulated. |