Abstract: | Reaction of CH3NH2 · BF3 and PCl5 yields CH3N(PCl3)(BCl3), (I), the behaviour of which to PCl5, pyridine and H2S is described. By using smaller amounts of PCl5, CH3N(PCl3)(BCl2F) (VI) is obtained. C6H5NH2 · BF3 reacts with PCl5 to give C6H5N(PCl3)(BCl3) (IX). Physical data, especially the NMR spectra of the new compounds, are given and discussed. |