Corrigendum |
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Authors: | Sylviane Sabo Bruno Chaudret Daniele Gervais |
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Institution: | Laboratoire de Chimie de Coordination du CNRS, associé à l≈Université Paul Sabatier, 205, route de Narbonne, 31400 Toulouse France |
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Abstract: | Reactions of NaMn(CO)3 with RuCl2(PMe3)4, RuCl2(dppm)2 and RuCl2(PPh3)3 lead either to an ionic species Ru2Cl3(PMe3)6]+Mn(CO)5]? or to metal—metal bonded RuMn compounds such as RuMn(μ-CO)2(CO)3(μ-dppm)2 Cl, and, quite unexpectedly, to the μ-phosphido complex RuMn(μ-PPh2)(CO)6(PPh3)2 via a hydride intermediate. |
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