Infrared matrix isolation evidence for the formation of (η5-cyclopentadienyl)tricarbonyl-molybdenum and -tungsten radicals in carbon monoxide matrices at 12 K |
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| Authors: | Khalil A Mahmoud Antony J Rest Helmut G Alt |
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| Institution: | Department of Chemistry, The University, Southampton SO9 5NH Great Britain;Laboratorium für Anorganische Chemie, Universität Bayreuth, D-8580, Bayreuth West Germany |
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| Abstract: | Infrared spectroscopic evidence including 13CO labelling and energy-factored force-field fitting is presented for the first time to show that the radicals (η5-C5H5)-M(CO)3? (M = MO, W) and HCO are produced on photolysis of (η5-C5H5)M(CO)3H complexes in CO matrices at 12 K. |
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| Keywords: | Author to whom correspondence should be addressed |
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