Disubstituted vinylidene complexes of iron and ruthenium: nucleophilic properties of ν1-acetylide ligands |
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Authors: | Steven Abbott Stephen G. Davies Peter Warner |
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Affiliation: | The Dyson Perins Laboratory, South Parks Road, Oxford OX1 3QY Great Britain |
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Abstract: | The η1-acetylide complexes (C5H5)ML2(CCR) (M Fe, Ru; L PPh3, L2 Ph2PCH2CH2PPh2) are nucleophilic at the β-carbon and react with a variety of mild electrophiles to yield the corresponding disubstituted vinylidene complexes [(C5H5)ML2 (CCR′) PF6. |
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