Study of the photolysis of arenetricarbonylchromium complexes by IR,UV and 1H and 13C NMR spectroscopy |
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| Authors: | E.A. Domogatskaya V.N. Setkina N.K. Baranetskaya V.N. Trembovler B.M. Yavorskii A.Ya. Shteinshneider P.V. Petrovskii |
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| Affiliation: | A.N. Nesmeyanov Institute of Organo - Element Compounds, Academy of Sciences of the USSR, Moscow U.S.S.R. |
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| Abstract: | The mechanism of photolysis of arenetricarbonylchromium complexes is investigated by a number of spectral techniques. Experimental data are obtained in favour of the formation during the ArCr(CO)3 photolysis of a multicenter complex, photodecay of which leads to the formation of chromium hexacarbonyl. A mechanism for the photolysis of arenetricarbonylchromium complexes is proposed. |
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