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Growth kinetics of amorphous hydrogenated silicon studied by pulsed rf discharge
Authors:Toshihiko Hamasaki  Masato Ueda  Masataka Hirose  Yukio Osaka
Affiliation:Department of Electrical Engineering, Hiroshima University, Higashihiroshima 724, Japan
Abstract:The growth rate and hydrogen bonding configuration of a-Si:H prepared by a pulsed rf discharge technique were measured as a function of repetition frequency. The result was compared with the case of the gas-phase polymerization of monomers C2H2, C2H4, and C2H6 in a pulsed rf discharge. From distinct difference between the pulsed-plasma depositions of a-Si:H and C:H films, it is concluded that the growth of a-Si:H proceeds through the heterogeneous reactions among chemical species on the substrate surface.
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