Neutral substituted carbonyl clusters of iridium. Synthesis and X-ray characterization of tri-μ3-carbonyl-μ-carbonylheptacarbonylpentakis(trimethylphosphite)-octahedro-hexairidium |
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| Authors: | Francesco Demartin Mario Manassero Mirella Sansoni Luigi Garlaschelli Maria Carlotta Malatesta Ugo Sartorelli |
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| Institution: | Istituto di Chimica Generale, Reparto Strutture, Via G. Venezian 21, 20133 Milano Italy;Dipartimento di Chimica Inorganica e Metallorganica, Via G. Venezian 21, 20133 Milano Italy |
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| Abstract: | The reaction of Ir6(CO)16 with P(OMe)3 in toluene yields Ir6(CO)11 P(OMe)3]5 which has been shown by X-ray diffraction to contain an octahedral cluster of iridium atoms bearing five terminal trimethylphosphite ligands, three face-bridging, one edge-bridging and seven terminal carbonyl groups. |
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