A model for photostructural changes in the amorphous AsS system

The photodarkening effect was studied in thin film, bulk glasses and powdered glasses of composition As₂₉S₇₁, As₄₀S₆₀ and As_42.5S_57.5. The amount of photodarkening produced in a sample depended strongly on the samples state and composition as well as temperature, incident light intensity and wavelength. Using Raman spectroscopy, vibrational bands at 231 and 491 cm^?1 (assigned to AsAs and SS bond vibrations) were found to be enhanced in photodarkened samples. We present a model in which photodarkening is due to the formation of As_n clusters (n ? 2) which are loosely coupled to the amorphous network.