Synthesis of cyclic polysulfides by the reaction of trimethylvinylsilane with S8 in the presence of Fe3(CO)12 |
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| Authors: | EA Chernyshev OV Kuz&#x;min AV Lebedev AI Gusev NI Kirillova NS Nametkin VD Tyurin AM Krapivin NA Kubasova |
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| Institution: | State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow U.S.S.R.;A.V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the U.S.S.R., Leninskii Prospekt 29, Moscow U.S.S.R. |
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| Abstract: | Reaction of trimethylvinylsilane with S8 in the presence of Fe3(CO)12 yielded the following compounds: S2Fe2(CO)6, S2Fe3(CO)9, 1-trimethylsilyl-2,3,4,5,6-pentathiacycloheptane, 1,4-di(trimethylsilyl)-2,3,6-trithiacycloheptane, 1,4-di(trimethylsilyl)-2,3,6,7-tetrathiacyclooctane. An X-ray analysis was performed for the two latter polysulfides. |
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