Crystal and molecular structure of tris(3,3,4,4-tetramethyl- 3,4-dihydrodiazete)bis(tricarbonylchromium), (N2C2Me4)3[Cr(CO)3]2 |
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Authors: | Bruna Bovio |
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Affiliation: | Dipartimento di Chimica Generale, Università di Pavia, Viale T. Taramelli 12, Pavia Italy |
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Abstract: | Crystals of C24H36N6O6Cr2 are monoclinic, a 15.380(3), b 13.965(2), c 14.459(3) Å, β 92.18(1)°; Z = 4; space group P21 with two independent molecules in the asymmetric unit. The crystal structure was determined from X-ray diffractometer data by direct methods and refined by least-squares methods to R = 0.066 for 2430 independent observed reflections. It consists of discrete molecules, in which each Cr atom is surrounded by three cis carbonyl groups and three cis nitrogen atoms of three 3,3,4,4-tetramethyl-1,2-diazetine ligands, in a deformed octahedral coordination. There is no evidence of intramolecular Cr ? Cr interaction. |
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