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Transformation of microcrystalline state of hydrogenated silicon to amorphous one due to presence of more electronegative impurities
Authors:Akio Hiraki  Yoshito Fukushima  Takashi Sato  Hideki Kiyono  Hitoshi Terauchi  Takeshi Imura
Affiliation:Department of Electrical Engineering, Osaka University, Suita, Osaka, 565 Japan
Abstract:When a slight fraction (~ 2 mol %) of N2 is added into H2, sputtering atmosphere for microcrystalline hydrogenated Si films, without changing other fabrication parameters, the amorphous film rather than microcrystalline one forms. The stabilization mechanism of the amorphous film of Si is discussed through TEM and IR observations of this kind of transformation from microcrystal to amorphous state.
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