Reactivity of thallium tris[tris(pentafluorophenyl)germyl] mercurate |
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Authors: | GA Razuvaev MN Bochkarev LV Pankratov |
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Institution: | Institute of Chemistry, Academy of Sciences of the U.S.S.R., Gorky U.S.S.R. |
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Abstract: | Metallic lithium and dibenzenechromium displace thallium from (Rf3Ge)3HgTl·1.5DME (Rf = C6F5, DME = 1,2-dimethoxyethane) to give (Rf3Ge)3HgLi·3DME and (Rf3Ge)4Hg]Cr(C6H6)2]2, respectively. Reactions of thallium germylmercurate with halides of metals and organometallics in DME/EtOH solution produce ionic compounds of (Rf3Ge)3Hg]? M+ type, which (depending on “M”) (a) may be isolated as pure compounds, (b) disproportionate, (c) form covalent derivatives Rf3Ge-m or (d) undergo alcoholysis. A general scheme for the reactions has been proposed. |
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