|
|||||
|
|
Chain elongation of monosaccharides by sequential cross metathesis and asymmetric dihydroxylation: expeditious approach to higher sugars |
|
| Authors: | Prithwish Kumar JanaSukhendu B Mandal Anup Bhattacharjya |
| Institution: | Chemistry Division, Indian Institute of Chemical Biology (A Unit of CSIR), 4, Raja S. C. Mullick Road, Jadavpur, Kolkata 700032, India |
| Abstract: | Glucose-derived alkenes were homologated via chain elongation to afford higher sugars by the application of cross metathesis with an alkene followed by Sharpless asymmetric dihydroxylation. Heptose, octose, nonose, and decose derivatives were expeditiously prepared by this method. |
| Keywords: | Monosaccharide Chain elongation Cross metathesis Asymmetric dihydroxylation Higher sugars Heptose Octose Nonose Decose |
| 本文献已被 ScienceDirect 等数据库收录！ | |