Ferromagnetic ordering and metamagnetism in malonate bridged 3D diamond-like and honeycomb-like networks: [Cu(mal)(DMF)]n and [[Cu(mal)(0.5pyz)].H2O]n (mal = Malonate Dianion,DMF = N,N-dimethylformamide,pyz = Pyrazine) |
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| Authors: | Liu Tian-Fu Sun Hao-Ling Gao Song Zhang Shi-Wei Lau Tai-Chu |
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| Institution: | College of Chemistry and Molecular Engineering, State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871, P.R. China. |
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| Abstract: | Two three-dimensional (3D) malonate bridged networks, Cu(mal)(DMF)](n) (1) and Cu(mal)(0.5pyz)].H(2)O](n) (2), have been synthesized in H(2)O-DMF solution. Compound 1 exhibits ferromagnetic ordering below 2.6 K (T(c)), and 2 displays a metamagnetic behavior below 3.2 K (T(N)). |
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