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Highly regioselective Pd-catalyzed allylic alkylation of fluorobis(phenylsulfonyl)methane |
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| Authors: | Xiaoming Zhao Dongge LiuShengcai Zheng Ning Gao |
| Affiliation: | Department of Chemistry, Tongji University, 1239 Siping Road, Shanghai 200092, PR China Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, PR China |
| Abstract: | A highly regioselective palladium-catalyzed allylic alkylation of fluorobis(phenylsulfonyl)methane has been studied. Using different allylic carbonates, a variety of terminal mono-fluoromethylated compounds were achieved in 85-99% yields with high regioselectivities. |
| Keywords: | Regioselectivity Palladium Allylic alkylation Fluorobis(phenylsulfonyl)methane |
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