Organopalladium approaches to prostaglandins. 2. Synthesis of prostaglandin endoperoxide analogs via π-allylpalladium additions to bicyclic olefins |
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| Authors: | RC Larock JP Burkhart K Oertle |
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| Institution: | Department of Chemistry, Iowa State University, Ames, Iowa 50011 U.S.A. |
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| Abstract: | A variety of prostaglandin endoperoxide analogos are readily available by addition of π-allylpalladium compounds to bicyclic olefins and subsequent treatment with alkenyl and alkynyl organometallics. Pronounced biological activity is evident in these compounds. |
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