Synthese der citromycinone stereoselektive öffnung eines epoxids zum cis-diol |
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Authors: | Karsten Krohn Bert Behnke |
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Affiliation: | Institut für Organische Chemie der Technischen Universität Braunschweig Schleinitzstraβe, D-3300 Braunschweig Germany |
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Abstract: | The citromycinone-derivatives and have been obtained by intramolecular Marschalk cyclisation of α-hydroxyaldehyde . An unexpected opening of epoxide to -diol was observed. By exclusion of the alternative formula structure is proposed for α-citromycinone. |
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