Stereoselective generation of Z-ketene S,N-acetal from S-alkyl onium salt of thioamide and its application to diastereoselective α-allylation of thioamide |
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| Authors: | Y Tamaru M Mizutani Y Furukawa O Kitao Z Yoshida |
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| Institution: | Department of Synthetic Chemistry, Kyoto University, Yoshida, Kyoto 606, Japan |
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| Abstract: | Highly diastereoselective α-allylation of thioamides has been achieved via S-allylation of thioamide, dehydrohalogenation, and thio-Claisen rearrangement sequences in one pot. |
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