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Solvolysis of 2-m-chlorobenzoyloxy-4-isopropyl-2h-1,4-thiazin-3-one generation of a stable carbocation
Authors:M Hojo  R Masuda  T Ichi  K Yoshinaga  M Yamada
Institution:Department of Industrial Chemistry, Faculty of Engineering, Kobe University, Rokkodai, Kobe, 657, Japan
Abstract:The title compound 2b undergoes nucleophilic substition reactions with exclusive aklyl-oxygen bond fission and its rate of solvolysis is highly sensitive toward change in polarity of solvents, as is shown by its highest m-value of all reported so far in logK - logk0 = mY.
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