Solvolysis of 2-m-chlorobenzoyloxy-4-isopropyl-2h-1,4-thiazin-3-one generation of a stable carbocation |
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Authors: | M Hojo R Masuda T Ichi K Yoshinaga M Yamada |
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Institution: | Department of Industrial Chemistry, Faculty of Engineering, Kobe University, Rokkodai, Kobe, 657, Japan |
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Abstract: | The title compound undergoes nucleophilic substition reactions with exclusive aklyl-oxygen bond fission and its rate of solvolysis is highly sensitive toward change in polarity of solvents, as is shown by its highest m-value of all reported so far in logK - logk0 = mY. |
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