Synthesis of conjugated nitroalkenes via nitroselenenylation of alkenes |
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| Authors: | Takashi Hayama Shuji Tomoda Yoshito Takeuchi Yujiro Nomura |
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| Affiliation: | Department of Chemistry, College of General Education, The University of Tokyo, Komaba, Meguro-ku, Tokyo, 153 Japan |
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| Abstract: | Addition of silver nitrite to 2-bromoalkyl phenyl selenide in the presence of mercury(II) chloride afforded 2-nitroalkyl phenyl selenide, which upon oxidative deselenenylation provided the conjugated nitroalkene in excellent yield. |
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