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On the reactivity-selectivity relationship in the solvolysis of several reactive alkyl halides |
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| Authors: | Rachel Ta-Shma Zvi Rappoport |
| Institution: | Department of Organic Chemistry The Hebrew University, Jerusalem 91004, Israel |
| Abstract: | In contrast to previous reports, the selectivities of four carbenium ions R+ towards N3? and H2O (log(KN3?/KH2O)) change more than the solvolytic reactivities (log Ksolv) of their rather reactive precursors RCl. |
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