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[2]Paracyclo[2](3,7)-p-tropoquinonophane
Authors:Akira Kawamata  Yoshimasa Fukazawa  Yutaka Fujise  Shô Itô
Affiliation:Department of Chemistry, Tohoku University Sendai 980, Japan
Abstract:The title compound 1 a novel cyclophane containing p-tropoquinone, was synthesized starting from 5-methoxytropolone and its physical properties were discussed comparing with those of 3,7-dimethyl-p-tropoquinone and p-benzoquinonophane. The reduced quinone character exhibited by 1 was ascribed to the intramolecular CT interaction and the deformation of the quinone ring.
Keywords:
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