[2]Paracyclo[2](3,7)-p-tropoquinonophane |
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Authors: | Akira Kawamata Yoshimasa Fukazawa Yutaka Fujise Shô Itô |
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Affiliation: | Department of Chemistry, Tohoku University Sendai 980, Japan |
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Abstract: | The title compound a novel cyclophane containing p-tropoquinone, was synthesized starting from 5-methoxytropolone and its physical properties were discussed comparing with those of 3,7-dimethyl-p-tropoquinone and p-benzoquinonophane. The reduced quinone character exhibited by was ascribed to the intramolecular CT interaction and the deformation of the quinone ring. |
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